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Beilstein J. Org. Chem. 2015, 11, 2737–2746, doi:10.3762/bjoc.11.295
Graphical Abstract
Figure 1: Triaryl-2-pyridylidene (PyC) and PyC-gold(I) complex (AuCl(PyC)).
Figure 2: Yield–time profiles of 4-(4-bromophenyl)-5-methylisoxazole (3ba) and methyl 2-iodobenzoate (5) with...
Scheme 1: Plausible reaction mechanism of gold-catalyzed oxidative C–H arylation of heteroarenes with arylsil...
Figure 3: ORTEP drawing of AuCl3(PyC) with 50% probability. Hydrogen atoms and solvent are omitted for clarit...
Scheme 2: Direct observation and isolation of carbene-gold(III) complex. Mes = 2,4,6-Me3C6H2, Xyl = 2,6-Me2C6H...
Beilstein J. Org. Chem. 2011, 7, 951–959, doi:10.3762/bjoc.7.106
Figure 1: Azepine frameworks found in natural products and pharmaceuticals.
Figure 2: Semihollow-shaped triethynylphosphine L1.
Figure 3: Time–conversion profiles for the gold-catalyzed cyclization of 4a with L1, X-Phos and IPr ligands.
Scheme 1: 8-exo-dig cyclization of sulfonamide 9.
Scheme 2: Isomerization experiments of 6a.
Figure 4: Possible pathway for the gold-catalyzed conversion of 4a into 5a.